Casting my vote with the people asking for some sort of flexible rubbery stuff. I think it's the main thing missing from the catalogue.
You could use it to print flexible lids for containers, soft shock-absorbing smartphone sleeves and portable harddrive wallets, anti-vibration feet and mountings for consumer electronics, flexible hinges and handgrips for composite pieces ... all sorts of cool things and components become possible.
But some of the applications would need it to be food-safe and perhaps dishwasher-safe (flexible lids for food containers, beakers, etc).
I suppose that for simple shapes, we could print a "negative" version as a mould, and use something like silicone or Sugru to make the components ourselves, at home ... but that means that anything we design that relies on those parts can't be sold in the Shapeways shop.