OK...I have just had a look at your video, firstly, nice job! Secondly congratulations on your ambition. That's quite a peice to learn silicone mold making on.
In complex molding one has to make sure all holes are filled. Then identify trouble spots, and think of ways of assembling molds around them that can be dissembled easily without damaging the cast material.
The problem with the crown is a) in how to create a mold in multiple parts and b) avoiding massive airlocks once you use the resin in the mold.
So the first part of a mold for the crown will be one that sits inside it, forming a support for those mold parts on the outside of the crown; and also acting as a mold wall in it's own right, preventing uncured silicone from entering the space it occupies. So firstly, you'd need to make the inside part of the mold first. So using an appropriate wax or clay, surround the outside of the crown with it, and make sure there are no gaps at all. so you can pour silicone into the core without it leaking out. Also include pegs in the arrangement to allow the surrounding silicone pieces to lock into this central part of the mold. Then create the outer parts .... creating individual mold walls for each part, as you create them, one after the other, is going to be tricky. Thin lego can help with wax or clay filling in the gap. You will have to match the edge of the walls to the spikes from the crown as no filler is going to attach itself to silicone. Again, using pegs as you go so the whole lot interlocks. Lastly, you are never going to be able to pour anything into a mold like that outside of a vacuum without trapping a huge amount of air. The way around this is to use a thixotropic agent in whatever resin you are going to use, and brush it on the inside of the molds, then put the mold together and brace it together, not too tight as this will warp the object. Basically if you do it right you won't have to pour any resin into the mold. it will all be there, at least in the thin and narrow parts. Of course, use a mold release spray between each wall as you pour silicone onto cured silicone!
I think your biggest problem will be the mold walls. They will be really fiddly. Good luck!