Is it possible to upload an image of the design?
I commonly use cellulose paint . Depending on your design spraying celulose and building up layers, sanding back, spraying, sanding, u get the picture. can product a flat surface. This wont work for designs that will constantly be flexed. As the paint will just crack.
For that i guess you would have to spray some sort of elastomeric paint.
This would flex but i doubt you could achieve a glossy finish. Although i have had no experience with this.
2pack paint is also an option. it dries hard and can be sprayed quite thick. Plus it polishes very well. But again has very little flex (if any)
I havent heard of any industry standards for gloss finishing fragile WSF, but I mainly use SLA (called FineDetail on Shapeways)
I have pondered on doing tests with Ultrasonic baths filled with sand or dipping in chemicals like chloroform (this would hopefully melt the surface slightly). But still to try them out.
Hope something in there helps.